Hexafluorophosphate

Hexafluorophosphate is an anion with chemical formula of PF⁻
₆. As a non-coordinating anion,^[1]^[2]^[3] it is a poor nucleophile. It is prone to decomposition with the release of HF.^[4]

Halide anions are easily replaced with PF⁻
₆ by reaction with silver hexafluorophosphate. The precipitation of insoluble silver halide helps drive this reaction to completion. Some room temperature ionic liquids, such as bmimPF₆, use PF⁻
₆ as a counterion.^[5]

Also, many imidazolium and formamidinium hexafluorophosphate salts are insoluble in water. The addition of ammonium hexafluorophosphate (NH₄PF₆) to an aqueous solution of the formamdinium/imidazolium salt results in a precipitate of the formamidinium/imidazolium hexafluorophosphate salt which can be gathered by filtration. This method can have advantages over the silver hexafluorophosphate method mentioned above in terms of expense and in systems where contamination with metal ions is strongly discouraged.

References

^ Attention: This template ({{cite doi}}) is deprecated. To cite the publication identified by doi:10.1016/j.inoche.2007.05.008, please use {{cite journal}} (if it was published in a bona fide academic journal, otherwise {{cite report}} with |doi=10.1016/j.inoche.2007.05.008 instead.
^ Julian A. Davies (1996). Synthetic coordination chemistry: principles and practice. World Scientific. p. 165. ISBN 9810220847.
^ Samuel Constant; Jerome Lacour (2005). Jean-Pierre Majoral (ed.). New trends in hexacoordinated phosphorus chemistry. New aspects in phosphorus chemistry. Vol. 5. Springer. p. 3. ISBN 354022498X.
^ Paul J. Dyson (2005). Tilmann J. Geldbach (ed.). Metal catalysed reactions in ionic liquids. Catalysis by metal complexes. Vol. 29. Springer Science & Business. p. 27. ISBN 140203914X.
^ Attention: This template ({{cite doi}}) is deprecated. To cite the publication identified by doi:10.1039/a806169f, please use {{cite journal}} (if it was published in a bona fide academic journal, otherwise {{cite report}} with |doi=10.1039/a806169f instead.

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[1] Attention: This template ({{cite doi}}) is deprecated. To cite the publication identified by doi:10.1016/j.inoche.2007.05.008, please use {{cite journal}} (if it was published in a bona fide academic journal, otherwise {{cite report}} with |doi=10.1016/j.inoche.2007.05.008 instead.

[2] Julian A. Davies (1996). Synthetic coordination chemistry: principles and practice. World Scientific. p. 165. ISBN 9810220847.

[3] Samuel Constant; Jerome Lacour (2005). Jean-Pierre Majoral (ed.). New trends in hexacoordinated phosphorus chemistry. New aspects in phosphorus chemistry. Vol. 5. Springer. p. 3. ISBN 354022498X.

[4] Paul J. Dyson (2005). Tilmann J. Geldbach (ed.). Metal catalysed reactions in ionic liquids. Catalysis by metal complexes. Vol. 29. Springer Science & Business. p. 27. ISBN 140203914X.

[5] Attention: This template ({{cite doi}}) is deprecated. To cite the publication identified by doi:10.1039/a806169f, please use {{cite journal}} (if it was published in a bona fide academic journal, otherwise {{cite report}} with |doi=10.1039/a806169f instead.

[1]

See also

References